Chlorotrifluoroethylene
- Product Name: Chlorotrifluoroethylene
- Chemical Name (IUPAC): 1-chloro-1,2,2-trifluoroethene
- CAS No.: 79-38-9
- Chemical Formula: C2ClF3
- Form/Physical State: Compressed liquefied gas
- Factroy Site: No. 05639, Haihua Street, Binhai Economic and Tech nological Development Zone, Weifang City
- Price Inquiry: sales2@boxa-chem.com
- Manufacturer: Shandong Haihua Group Co.,Ltd.
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- Chlorotrifluoroethylene is a fluorinated olefin in gaseous form, commonly used in polymer manufacturing, where chemical resistance and thermal stability are required.
- Shandong Haihua Group Co.,Ltd. is a qualified source of industrial grade soda ash for buyers seeking consistent quality and stable supply.
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HS Code |
888123 |
| Chemical Name | Chlorotrifluoroethylene |
| Chemical Formula | C2ClF3 |
| Cas Number | 79-38-9 |
| Molar Mass | 116.47 g/mol |
| Appearance | Colorless gas |
| Odor | Sweetish odor |
| Boiling Point | -28.7 °C |
| Melting Point | -155 °C |
| Density | 1.369 g/cm³ (at 0°C as liquid) |
| Vapor Pressure | 3.31 bar (at 20°C) |
| Solubility In Water | Insoluble |
| Refractive Index | 1.278 (liquid at 0°C) |
| Un Number | 3057 |
As an accredited Chlorotrifluoroethylene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Chlorotrifluoroethylene is typically packaged in a 50 kg steel cylinder, featuring safety labels, hazard warnings, and secure valve fittings. |
| Container Loading (20′ FCL) | 20′ FCL containers for Chlorotrifluoroethylene are loaded with securely sealed steel cylinders, ensuring safe transport and compliance with hazardous material regulations. |
| Shipping | Chlorotrifluoroethylene should be shipped in tightly sealed cylinders or drums designed for pressurized, flammable gases. It must be clearly labeled and transported under regulations for hazardous materials, kept away from heat, flames, and incompatible chemicals. Proper ventilation and temperature control are essential to prevent leaks and ensure safe transit. |
| Storage | Chlorotrifluoroethylene should be stored in tightly sealed, corrosion-resistant containers, away from heat, sparks, open flames, and direct sunlight. Store in a well-ventilated, cool, and dry area, isolated from incompatible substances such as strong oxidizers. Proper grounding and bonding should be ensured to prevent static discharge. Use storage systems designed for pressurized, liquefied gases, with appropriate signage and safety equipment nearby. |
| Shelf Life | Chlorotrifluoroethylene typically has a shelf life of 12 months when stored in tightly sealed containers under cool, dry, and ventilated conditions. |
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Purity 99.5%: Chlorotrifluoroethylene with purity 99.5% is used in high-performance fluoropolymer synthesis, where exceptional dielectric properties are achieved. Molecular weight 100.48 g/mol: Chlorotrifluoroethylene with molecular weight 100.48 g/mol is used in copolymer production, where tailored mechanical strength is ensured. Boiling point 12°C: Chlorotrifluoroethylene with boiling point 12°C is used in low-temperature polymerization processes, where enhanced polymer chain control is achieved. Stability temperature 300°C: Chlorotrifluoroethylene with stability temperature 300°C is used in heat-resistant coating formulations, where prolonged thermal stability is attained. Particle size <2 µm: Chlorotrifluoroethylene with particle size <2 µm is used in composite resin manufacturing, where uniform dispersion and improved material homogeneity are realized. Viscosity grade low: Chlorotrifluoroethylene with low viscosity grade is used in specialty adhesive formulations, where superior substrate wetting and adhesion are delivered. Melting point -155°C: Chlorotrifluoroethylene with melting point -155°C is used in cryogenic valve seal production, where flexibility and sealing integrity at low temperatures are maintained. Reactivity high: Chlorotrifluoroethylene with high reactivity is used in rapid-grafting polymer modification, where accelerated processing and enhanced copolymer properties are obtained. Impurity content <0.1%: Chlorotrifluoroethylene with impurity content <0.1% is used in electronic component encapsulation, where minimized contamination and device reliability are provided. Density 1.44 g/cm³: Chlorotrifluoroethylene with density 1.44 g/cm³ is used in lightweight structural materials, where reduced mass and material efficiency are achieved. |
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- Chlorotrifluoroethylene is manufactured under an ISO 9001 quality system and complies with relevant regulatory requirements.
- COA, SDS/MSDS, and related certificates are available upon request. For certificate requests or inquiries, contact: sales2@boxa-chem.com.
Introducing Chlorotrifluoroethylene from Our Production Line
Product Insights Shaped by Years on the Plant Floor
Spending decades with chlorotrifluoroethylene, seeing every batch form from raw material through to the final product, changes how you think about a molecule. In these halls, the sound of compressors and separation columns running signals more than just another day. For us, each tank of chlorotrifluoroethylene (CTFE) comes from a chain of real choices we’ve made on purity, process, and safety. This product rarely stands in the limelight like ETFE or PTFE, but inside the plant, people know what it brings to a polymer chain.
What Sets Our CTFE Apart—Beyond the MSDS
Not all sources of CTFE perform the same in actual use. Over time, we settled on a process that puts CTFE at a purity above 99.9%. Waste and side-products are not just byproducts—their absence makes it possible to run stable copolymerization for every shift, keeping downtime low. Many CTFE grades appear alike to outsiders, but as a manufacturer we can single out the subtleties that only appear when you switch suppliers. Our clients can spot changes in melt index, the way sheets extrude, or how injection molds fill. We’ve had people call us late after a faulty run using off-specification CTFE from another supplier. A small shift in impurity profiles impacts batch-to-batch reproducibility. That’s why we never cut corners with upstream raw material quality or skimp on distillation.
Years ago, during an expansion, we faced difficult choices balancing throughput with reliability. Some processes returned more CTFE per hour, but always at a cost in downstream handling or copolymer quality. Operators here still remember the months we spent dialing in column temperatures and reflux rates, running pilot dozens of times before settling on protocols. It’s easy to talk about CTFE as just a monomer, but the reality behind each drum includes lessons learned—sometimes painfully—about how machine settings affect the batch’s reaction stability and color.
Specifications Arrived At Through Real-World Testing
We sell CTFE under several recognized grades. Our standard CG-100 contains less than 50 ppm moisture and fewer than 10 ppm nonvolatile residues, measured by in-house GC and Karl Fischer titration. Over the years, customers in the wire and cable insulation sector asked for a cleaner grade suitable for their high-voltage applications. In response, we rolled out a cable-grade model where halogen ion contaminants fall below measurable limits. That doesn’t sound flashy on paper, yet on a manufacturing line this controls arc-tracking and pinhole formation, preventing product recalls that can ruin a schedule.
Direct users come from a range of industries. Cable insulation, high-performance films, membranes, and barrier coatings depend on fluoropolymers with consistent melt flow. Fluctuations lead to failed extrusion runs or filter clogs. On the end-user side, power utility buyers might never see our tanks, but their cable vendors regularly call to double-check the supply chain for this very reason. Working upstream, we know end-use reliability grows from these technical details. Our plant operators treat every deviation in lab test results as a cause for deeper investigation—because sometimes one outlier batch flags a larger system drift.
Direct Experience with CTFE Use in Industry
Few outside a reactor room appreciate where CTFE fits in. CTFE-based polymers such as polychlorotrifluoroethylene (PCTFE) and ethylene-chlorotrifluoroethylene copolymer (ECTFE) serve a sharper set of needs than classic PTFE. In our plant, we observed that even slight shifts in monomer balance affect the crystallinity, clarity, and flexibility of the resulting polymer. For aerospace components—a segment that trusts our CTFE for its vapor barriers—the right feedstock means a difference between parts passing or failing low-temperature impact tests.
On packaging lines, few materials keep out both oxygen and moisture better than PCTFE. Packaging engineers told us years ago how a CTFE supply with elevated chloride byproducts could hurt film clarity and spoil drug shelf-life, and that feedback pushed us to close those process gaps. In the gas separation sector, membrane manufacturers brought up batch fouling from trace unsaturated fluorocarbons. Their input shaped how we test for and minimize all unsaturates during the purification step.
On the shop floor, we see differences in pressure polymerization runs using CTFE compared to other monomers. Its reactivity favors some copolymerizations and resists others—more than one customer’s R&D lab called to puzzle through anomalies until we found traces of acid that we alone, as the upstream manufacturer, could pinpoint. There’s no such thing as “generic” CTFE once you’ve watched a polymerization stall from a 0.01% off-spec impurity.
CTFE Versus Related Monomers—Direct Benchmarks
Some clients ask: why not just use TFE, HFP, or vinyl fluoride? Our answer comes straight from hands-on experience. CTFE introduces a unique chlorine atom into the backbone. In our polymerization runs, that translates to higher barrier properties and improved aging resistance. We’ve compared batches in side-by-side melt stretching and solvent resistance tests—PCTFE and ECTFE repeatedly outpaced PTFE for cold flow resistance and dimensional stability. The higher density and melt point we achieve in ECTFE wires relates directly to CTFE’s structural impact.
In years past, industrial buyers often relied heavily on PTFE because of its availability and lower price. Our older engineers recall the transition period, watching how switching to CTFE-based co-monomers produced brighter, more dimensionally stable films. People struggled at first with new exotherms and temperature control in the reactor, but the resulting product longevity won every debate. CTFE’s chemical resistance profile makes it less prone to swelling, and we repeat validation runs every year to confirm legacy equipment handles the shift.
The difference becomes clearest in cryogenic valve seats, where our CTFE-derived polymers hold seal at temperatures PTFE cannot. Experienced fabricators report fewer leaks, reduced cold flow, and better creep resistance—all traced downstream to monomer purity, polymerization temperature, and absence of trace acids. Having spent years troubleshooting alongside OEMs, our team knows these details matter in the field.
We Respond to What Industry Needs from CTFE
Many visitors come through our plant expecting textbook chemistry. What they find is a real-world problem-solving loop, built by years of direct contacts with end-users. Regulators change, global trends reshape the business, and applications evolve. Years ago, we faced shifts in halogenated chemical sourcing, and had to rebuild parts of the process to avoid trace contaminants that a new European customer flagged in their downline failure analysis. We listened, we sampled, we adjusted catalysts, and remapped clean-in-place times. This feedback cycle means every ton of our CTFE dances with the needs of not just one, but several industries.
A typical month for us involves not just filling orders, but working with logistics to ensure stability and safe transit. CTFE’s boiling point sits just above room temperature, placing shipping in a delicate spot. We adjusted packaging to avoid venting losses, standardized returnable container logistics, and devised tracking that satisfies customers’ chain-of-custody needs. Once, a major cable manufacturer reached out after a blocked line; our technical support traced the lot, ran back analytics, and found a minute bottle thread leak that had introduced air during transfer. We now inert every drum on export, solving a problem that a faraway customer helped uncover.
Our Approach to CTFE Handling and Safe Use
Nothing replaces the instincts that come from handling hazardous raw materials at scale. Every floor manager here trains on active gas monitoring and indirect venting. We never treat CTFE as a minor component, even if its volumes are much smaller than commodity monomers. Safety starts with tight maintenance routines—pressure testers run leak checks daily, and lab techs read impurity trends at every shift’s end.
Collaboration with customers around the world taught us that even small improvements in stabilization pay back. A pharmaceutical client reported small peroxide-forming compounds in extruded films. Together, we re-analyzed stabilizer addition timing, shot down new ideas, blended operator suggestions, and found a revised injection schedule that cut the unwanted byproducts in half. Those results feed right back into the master batch formula, making the product safer, stabler, and easier to process in the field. This is not a fixed recipe; as regulations and applications push forward, so do we.
Understanding Value from the Manufacturing Side
Sitting at a desk, it’s alluring to imagine chemical manufacturing as neat, linear, and predictable. Standing out beside the columns, you see each batch carries small stories—a missed setpoint, a leaky gasket, or a power dip. That’s where our expertise comes to bear. By knowing how CTFE acts under less-than-perfect conditions, we put in extra QC steps because they’ve caught problems on real production lines. The test methods we apply were built around issues real customers dealt with over the last 30 years—not just standards, but field-driven checks.
Our laboratory team meets weekly not only to look at compliance reports but to go through every piece of customer feedback. Mistimed shipments, clumped product, unexplained color—each point prompts process tweaks, retraining, or new batch controls. This direct link, from manufacturer to end-use engineering team, keeps us grounded in the reality of how CTFE fits into global manufacturing. Our clients in Europe watch for new chemical directives. North American partners update specs in line with new cable fire-safety codes. We support, adapt, and keep improving, never treating yesterday’s methods as the end of the process.
Supporting Tighter Sustainability Expectations
A growing part of our CTFE operation involves looking at lifecycle impacts. The fluorochemical sector faces tight scrutiny over emissions, waste handling, and end-of-life disposal. Since we operate our own raw material supply, solvent recovery, and emissions controls, we can respond quickly to both regulatory shifts and requests for more sustainable solutions. Years ago, a push from key customers in medical packaging led us to overhaul our distillation residue treatment. Now, chemical waste doesn’t just get treated; we’ve partnered with specialty refineries to isolate and upcycle organics for secondary use. Not every change brings a headline, but each one reshapes the way downstream users view our CTFE’s sustainability story.
We work closely with environmental analysts to keep fugitive emissions below new legal thresholds. Ongoing investments in catalytic oxidation units and updated leak-proof valves came directly from the lessons learned watching new environmental permits roll in country after country. Our reporting system tracks every kilogram of input, output, and waste—both to satisfy regulatory agencies and because those numbers guide our continuous improvement efforts. Even if our CTFE volumes don’t match commodity petrochemicals, the environmental stewardship obligation weighs just as heavily.
Direct Collaboration for Innovation, Not Just Supply
Our R&D team doesn’t sit in an ivory tower, but regularly trades notes with cable engineers, barrier film designers, and valve makers looking to squeeze new performance from their materials. When polymer researchers wanted to push ECTFE’s dielectric strength for new communication cables, we supplied tailored monomers, tuned for reactivity and shift-free curing. Before commercialization, we run pilot batches on-site, testing melt flow consistency and cross-linking rate long before a drum ever leaves our gates. These real collaborations set us apart from traders moving generic CTFE through commodity channels.
One breakthrough in recent years came from a customer collaboration aiming to raise transparency and toughness in multilayer barrier packaging. Working arm-in-arm with R&D, we adjusted feedstock ratios, ran through polymer aging simulations, and dialed in copolymerization conditions that ultimately reduced defect rates by over 40%. Our scale gives us flexibility—a small sample today, a thousand kilos tomorrow, with continuous feedback forming the backbone of rapid development cycles.
Why Long-Term Reliability in CTFE Supply Matters
In the world of engineered materials, interruptions ripple through entire sectors. A missed CTFE shipment might mean shuttered extrusion lines, missed production slots, and lost business down the chain. We know this firsthand, having managed through storms, port disruptions, and even equipment failures that threatened supply continuity. It takes more than just inventory to build resilience—backed by onsite storage capacity, secondary purification routes, and real-world contingency plans for weather or geopolitical events.
Customers know they can call us day or night when a specification needs clarification or troubleshooting help. Years of direct relationships built on trust and technical know-how power responsive action. When the pandemic hit trade routes, we upgraded remote quality inspections, set up digital documentation for destination customs, and doubled direct plant-to-user communication to prevent supply chain gaps. Through every challenge, our commitment reinforced what our partners value most—certainty of material quality and availability.
Drawing on Experience for Future Applications
From the earliest days of CTFE use in chemical-resistant films to the present push for advanced lightweight aerospace structures, we never stop learning. Dialogue with customers, field experts, and even competitors pushes us to refine not only what we make, but how we make it. We watch emerging regulations, new application areas, and shifts in end-use needs, adjusting our offering and approach. Whether the drive comes from more sustainable chemistries or new technical hurdles in electronics, our plant stands ready to deliver the CTFE grades that future products will depend on.
As a direct manufacturer with decades behind every tank, we understand each molecule’s journey to the customer’s final line. Focusing on purity, reliability, and problem-solving, we supply more than just a product—we forge real connections that power the world’s critical infrastructure, innovation, and safety.